曼尼希碱季铵盐酸化缓蚀剂的合成及性能

合成了一种新型的曼尼希碱季铵盐(BMQA)酸化缓蚀剂,通过静态失重法测试了缓蚀剂在不同浓度盐酸中的缓蚀性能。结果表明,90℃下,缓蚀剂BMQA在15%盐酸中加入0.1%,18%盐酸中加入0.2%,28%盐酸中加入0.5%,N80钢的腐蚀速率都能小于4g·m-2·h-1。极化曲线测试表明该缓蚀剂是抑制阳极为主的混合型缓蚀剂,遵循Langmuir吸附等温式,能自发在金属表面进行化学吸附。     

大型石油焦回转窑煅烧过程三维数值模拟

通过采用商业软件Fluent12.1建立了大型石油焦回转窑窑内煅烧过程三维数值模拟模型,获得了在正常操作状态下窑内温度场、流场和物质浓度场的分布状况。计算结果显示,由于窑尾变径的影响,窑尾气流速加快,影响石油焦粉料的带出;窑内石油焦的升温速度较快,导致挥发分在靠近窑尾段大量析出,窑尾温度偏高,大量挥发分没有及时在窑内完全燃烧;由于窑头漏风的影响,造成煅烧带炭质烧损的增加。     

金属表面席夫碱缓蚀剂自组装膜的制备及性能研究现状

席夫碱是由伯胺与活性羰基缩合而成的含有甲亚胺活性基团-RC=N-的一类有机化合物,能在金属表面发生化学吸附反应而形成结构稳定、排列紧密有序的自组装膜(SAMs);SAMs是一种有缓蚀性能的单分子膜,对基底金属有良好的防腐蚀作用.本文综述了近年来席夫碱类自组装膜的制备方法及自组装膜的表征技术,进一步概述了分子模拟及拓扑结...     

N含量对13Cr超级马氏体不锈钢耐蚀性的影响

对13Cr超级马氏体不锈钢进行氮合金化,采用淬火-配分热处理工艺,研究了不同N含量对13Cr钢的微观组织及电化学腐蚀行为的影响。结果表明:随N含量增加,板条马氏体组织表现出明显的细化行为,奥氏体含量增加,且有VN生成,从而防止N与Cr结合生成Cr₂N,促使Cr在材料表面形成以Cr₂O₃为主的致密腐蚀产物膜,提高材料耐蚀性;试验钢表面以局部腐蚀为主,试样表面有点蚀发生。随着N含量的增加,形成腐蚀产物膜的孔隙度减小;表面钝化膜为双电层结构,增加了钝化膜的稳定性,点蚀坑数量明显减少且变小;提高N含量有利于试样耐点蚀性能的改善,0.35%N试验钢表面腐蚀产物附着牢固,平整且致密,晶粒大小均匀,可起到良好的保护作用。     

电位对核电用镍基合金传热管应力腐蚀破裂的影响

概述了电位对600、690和800合金应力腐蚀破裂敏感性的影响。     

Fe_(16)N_2 的沉淀效应

含氮马氏体室温时效和低于１７５℃回火时有Ｆｅ１６Ｎ２沉淀。Ｆｅ１６Ｎ２的沉淀效应显著,于１００℃回火时沉淀效应最大,ＨＶ、ｃ／ａ比和α（２２０）半高宽均达到最大值。Ｆｅ１６Ｎ２淀淀具有很高的强化效果,纯铁和２０钢渗氮后于１００℃回火,硬度分别提高５８％和６２％。Ｆｅ１６Ｎ２的沉淀效应具有广泛的应用前景     

面向大批量定制产品的快速设计系统的研究

为提高定制企业对市场的快速响应能力，需要建立大批量定制产品的功能-结构映射关系，本文分析了使用产品族体系组织产品设计资源的方法，提出了信息系统用来表达定制产品族设计知识的“三层次模型”及其实现过程，并在Unigraphics及其知识融合UG/KF平台上采用KBE与CAD集成的方式，为电梯轿厢产品开发了以产品知识库为中心的集成化的快速设计系统。     

Effects of nitrogen content on structure and electrical properties of nitrogen-doped fluorinated diamond-like carbon films

Nitrogen-doped fluorinated diamond-like carbon (FN-DLC) films were prepared on single crystal silicon substrate by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) under different deposited conditions with CF₄, CH₄ and nitrogen as source gases. The influence of nitrogen content on the structure and electrical properties of the films was studied. The films were investigated in terms of surface morphology, microstructure, chemical composition and electrical properties. Atomic force microscopy (AFM) results revealed that the surface morphology of the films became smooth due to doping nitrogen. Fourier transform infrared absorption spectrometry (FTIR) results showed that amouts of C=N and C

N bonds increased gradually with increasing nitrogen partial pressure r (r=p(N₂)/p(N₂+CF₄+CH₄)). Gaussian fit results of C 1s and N 1s in X-ray photoelectron spectra (XPS) showed that the incorporation of nitrogen presented mainly in the forms of β-C₃N₄ and a-CN_x (x=1, 2, 3) in the films. The current?voltage (I?V) measurement results showed that the electrical conductivity of the films increased with increasing nitrogen content.     

In-situ weld-alloying plasma arc welding of SiCp/Al MMC

Plasma arc welding was used to join SiCp/ml composite with titanium as alloying filler material. Microstructure of the weld was characterized by an optical microscope. The results show that the harmful needle-like phase Al4C3 is completely eliminated in the weld of SiCp/Al metal matrix composite（MMC） by in-situ weld-alloying/plasma arc welding with titanium as the alloying element. The wetting property between reinforced phase and Al matrix is improved, a stable weld puddle is gotten and a novel composite-material welded joint reinforced by TiN, AlN and TiC is produced. And the tensile-strength and malleability of the welded joints are improved effectively because of the use of titanium.     

In对Sn-8Zn-3Bi无铅钎料润湿性的影响

首先采用铺展法测试了Sn-8Zn-3Bi-(0～5)In钎料合金的铺展性.结果表明,少量In的加入提高了钎料的润湿性.当In含量达到0.5%时(质量分数,下同),钎料在铜基底上的铺展面积最大.采用气泡最大压力法对Sn-8Zn-3Bi-(0～1.5)In钎料熔体进行了表面张力测试.加入0.5%的In大大降低了Sn-8Zn-3Bi钎料熔体的表面张力,但进一步增加In的含量导致熔体表面张力增大.最后采用润湿平衡法对上述钎料进行了润湿力测试.结果表明0.5%In的加入使合金的润湿力达到最大,其原因是钎料/铜界面的界面张力减小.